HDPE 遼寧華錦化工 A4009MFN1325

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品牌 遼寧華錦化工 規(guī)格型號 HDPE
編號 A4009MFN1325 計量單位 1公斤
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HDPE 軒源塑膠供應(yīng)13168406869 遼寧華錦化工 A4009MFN1325

       一般的HDPE熔點(diǎn)為142℃,分解溫度為300℃;注塑溫度的可調(diào)區(qū)間較大。注塑時,一般使用溫度為180℃--230℃;因是烯烴類塑料,它不吸水,生產(chǎn)時,不需烘干,但為了產(chǎn)品質(zhì)量,可用60℃溫度烘干1hr,以排出浮水;聚乙烯的熔體粘度大,流長比小,薄壁制品可能缺膠,因此,澆口和流道相對較大;制品易帶靜電,表面易吸埃。收縮率為16‰;溢邊值為0.05mm。
The melting point of HDPE is 142 ℃, decomb temperature 300 ℃; the injection temperature adjustable interval larger. Injection molding, general use temperature is 180 ℃ --230 ℃; because the olefine plastic, it does not absorb water, production, without drying, but to the quality of the products, can be 60 ℃ drying 1hr, to discharge the water; the melt viscosity of polyethylene, flow length ratio is small, thin-walled products may lack of glue, therefore, gate and runner is relatively large; products easy with static electricity, surface easy to absorb. Shrinkage rate was 16 ‰; overflow boundary value for 0.05mm.

 

       深入納米碳酸鈣對HDPE的增強(qiáng)增韌研究結(jié)果表明:a.納米級碳酸鈣在未經(jīng)表面處理的情況下,與HDPE仍具有一定的粘接作用力,對HDPE有增強(qiáng)增韌作用;b.現(xiàn)有表面處理劑對納米碳酸鈣與HDPE相界面粘接作用的改善不大,但能促進(jìn)碳酸鈣粒子在基體中的均勻分散,顯著減少碳酸鈣增強(qiáng)增韌HDPE的用量。表面處理的碳酸鈣在含量為4%~6%時,復(fù)合材料的沖擊強(qiáng)度即可以提高1倍,同時其屈服強(qiáng)度及模量也均有所提高。研究Caco3/HDPE復(fù)合體系時觀察到輕質(zhì)碳酸鈣填充HDPE的斷口形貌為典型的“帶狀結(jié)構(gòu)”,重質(zhì)碳酸鈣填充HDPE為“絮狀結(jié)構(gòu)”,兩者都有利于材料韌性的提高,但“帶狀結(jié)構(gòu)”吸收的沖擊能不一定比“絮狀結(jié)構(gòu)”的高。
Deep nano calcium carbonate on HDPE reinforcing and toughening research results show that: A. nanometer calcium carbonate without surface treatment, and the HDPE still has the adhesive force certain, a reinforcing and toughening effect on HDPE; not much existing B. agents on the surface treatment of nano calcium carbonate and HDPE interface adhesive effect, but can promote the calcium carbonate particles in the matrix of the unib dispersion, significantly reduce the amount of calcium carbonate reinforced and toughened HDPE. Surface treated calcium carbonate in the content of 4%~6%, the impact strength of the composites can be increased by 1 times, while the yield strength and modulus also increased. Study on Caco3/HDPE composite system was observed when light calcium carbonate filled HDPE fracture morphology typical of the "banded structure", heavy calcium carbonate filled HDPE "flocculent structure", both to the improvement of material toughness, but "banded structure" to absorb the shock of energy is not necessarily better than the "high flocculent structure".

 

HDPE 軒源塑膠供應(yīng)13168406869 遼寧華錦化工 A4009MFN1325

        HDPE是一種結(jié)晶度高、非極性的熱塑性樹脂。原態(tài)HDPE的外表呈乳白色,在微薄截面呈一定程度的半透明狀。PE具有優(yōu)良的耐大多數(shù)生活和工業(yè)用化學(xué)品的特性。某些種類的化學(xué)品會產(chǎn)生化學(xué)腐蝕,例如腐蝕性氧化劑(濃硝酸),芳香烴(二甲苯)和鹵化烴 (四氯化碳)。
HDPE is a high degree of crystallinity, non-polar thermoplastic resin. The original state of HDPE milky white appearance, with a certain degree of translucent at thin section. PE has excellent chemical resistance properties with the most life and industry. Some kinds of chemicals will produce chemical corrosion, such as corrosive oxidizer (nitric acid) (Er Jiaben), aromatic hydrocarbons and halogenated hydrocarbons (carbon tetrachloride).

 

        使用無機(jī)剛性粒子對高分子材料進(jìn)行增韌,是近年來高分子材料科學(xué)領(lǐng)域出現(xiàn)的一項(xiàng)重要的新技術(shù),目前對剛性無機(jī)粒子增韌的基本條件初步認(rèn)識有三條:1、剛性粒子與樹脂基體之間要有良好的界面粘接力,使應(yīng)力更容易通過界面?zhèn)鬟f,界面粘接的好壞與粒子的冷拉有直接影響;2、被增韌基體本身應(yīng)具有一定韌性?;w的韌性使得它在共混合金受力時易于屈服形變,產(chǎn)生對剛性粒子的靜壓力,并使其發(fā)生塑性形變以吸收更多的沖擊能量;3、剛性粒子要有恰當(dāng)?shù)某叽?,剛性粒子粒徑要小且濃度要達(dá)到一定值才能增韌。
The use of polymer materials toughened rigid inorganic particles, is an important new technology emerges in the field of Polymer Materials Science in recent years, the basic conditions of rigid inorganic particle toughened preliminary understanding has three: have a good interfacial adhesion between the 1, rigid particles and resin matrix, the stress more easily through the interface transfer, directly affects the particle and the interfacial adhesion of cold drawing; 2, by toughening matrix itself should have certain toughness. The toughness of the matrix makes it easy to yield debation in the blend stress, static pressure on the rigid particles, and the occurrence of plastic debation to absorb more impact energy; 3, the rigid particles must have the appropriate size, rigid particle size to small and concentration to reach a certain value to toughening.

 

HDPE 軒源塑膠供應(yīng)13168406869 遼寧華錦化工 A4009MFN1325
       HDPE是一種由乙烯共聚生成的熱塑性聚烯烴。雖然HDPE在1956年就已推出,但這種塑料還沒達(dá)到成熟水平。這種通用材料還在不斷開發(fā)其新的用途和市場。我國國內(nèi)高密度聚乙烯(這里的高密度聚乙烯不包括全密度聚乙烯裝置生產(chǎn)的高密度聚乙烯)的生產(chǎn)商有中石油、中石化、中海油三大企業(yè),截至2006年年底,屬于中石油的高密度聚乙烯裝置有4套,即蘭州石化高密度聚乙烯裝置、大慶石化高密度聚乙烯裝置、遼陽石化高密度聚乙烯裝置、吉林石化高密度聚乙烯裝置
HDPE is a polyolefin produced by copolymerization of ethylene thermoplastic. Although HDPE in 1956 has been launched, but the plastic hasn't reached the mature level. This versatile material continues to develop its new uses and markets. China's domestic HDPE (high density polyethylene high density polyethylene here do not include the full density polyethylene device production) producers in the oil, Sinopec, CNOOC three large enterprises, as of the end of 2006, high density polyethylene device belongs to the oil in 4 sets, namely Lanzhou Petrochemical HDPE device, Daqing Petrochemical HDPE device, Liaoyang Petrochemical HDPE device, Jilin Petrochemical HDPE device
 
        從復(fù)合材料的觀點(diǎn)分析,若粒子剛硬,且粒子與數(shù)值界面結(jié)合緊密,如粒子經(jīng)特定的改性劑處理,則助劑粒子也能承受拉應(yīng)力,起增強(qiáng)改性的作用。在塑料材料中加入無機(jī)填料,不僅可以明顯降低材料成本,而且還可以適當(dāng)改善材料的力學(xué)模量、耐熱性能和表面硬度等材料性能,然而,在塑料材料中加入無機(jī)填充材料后一般都會使材料性能變脆,缺口沖擊韌性下降,材料的使用性能收到明顯影響。故其填充材料的加入量不宜過多一般加入量在10%左右,因此這也限制了該種改性方法的進(jìn)一步深入發(fā)展。如何能在既增加填充量,明顯降低塑料材料生產(chǎn)成本的同時,也顯著提高其材料的缺口沖擊韌性、力學(xué)模量和耐熱性等,提高塑料材料的使用性能,已經(jīng)成為近年來人們所關(guān)注的熱門話題“剛性填料粒子增韌塑料材料”。
Waka Kotake analysis, from the viewpoint of the composite materials, and the particle and numerical interfacial bond, such as particles by modifying agent to treat specific, is auxiliary particle can also bear the tensile stress, enhancing modification effect. The addition of inorganic filler in plastic material, not only can reduce the material cost, but also can improve the material's mechanical modulus, heat resistance and surface hardness of material properties, however, the addition of inorganic filling material will generally make the material properties become brittle in plastic material, the notched impact toughness decreased, the properties of materials received obvious effect. The filling material in an amount of not too much general content about 10%, so this also limits the further development of the modified b. How can both increase filling amount, reduce plastic materials production costs at the same time, also improve the material notch impact toughness, mechanical property and heat resistance, improve the use of plastic material properties, has become a hot topic concerned by people in recent years "rigid filler particle toughened plastics materials".
 
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